Brad Pitt and Angelina Jolie

The electricity between Angelina Jolie and Brad Pitt on the set of Mr. and Mrs. Smith made rumor mills turn. During the time of filming, Brad was still married to Jennifer Aniston while Jolie just got separated from Billy Bob Thornton. Jolie then confirmed in a magazine interview that she and Brad had already developed feelings for each other. She shared that they both had a strange friendship and partnership that happened all of a sudden.

When filming wrapped up, the pair then realized that their relationship might have meant something even more serious and needed to be taken to the next level. Later on, Pitt and Aniston decided to separate with Jennifer finalizing their divorce a few months later. In that same year, Pitt and Jolie were spotted having what appeared to be a family holiday in Kenya together with their adopted son, Maddox.